What is pH and pOH? How are they both related?

Key Points

  • pH is logarithmic measurement of the hydrogen ion concentration in a solution.
  • pH = -log10[H+]
  • A pH change of 1 represents a 10 fold change in the hydrogen ion concentration.
  • As the pH increases the hydrogen ion concentration [H+] decreases.
  • As the pH increases the hydroxide ion concentration [OH-] increases.
  • pOH is a logarithmic measurement of the hydroxide ion concentration in a solution.
  • pOH = -log10[OH-]
  • The concentration of hydrogen ions multiplied by the concentration of hydroxide ions in an aqueous solution is a constant.
  • The dissociation constant for water is Kw = [H+] [OH-] = 1 x 10-14 at 25°C
  • pH + pOH =14

pH and POH table

pH

-1

0

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

[H+]

101

100

10-1

10-2

10-3

10-4

10-5

10-6

10-7

10-8

10-9

10-10

10-11

10-12

10-13

10-14

10-15

[OH-]

10-15

10-14

10-13

10-12

10-11

10-10

10-9

10-8

10-7

10-6

10-5

10-4

10-3

10-2

10-1

100

101

pOH

15

14

13

12

11

10

9

8

7

6

5

4

3

2

1

0

-1

Kw

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

10-14

 

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